Free download Atkins’ Physical Chemistry (9th edition) by Peter Atkins and Julio de Paula in .pdf published by W. H. Freeman and Company in 2010.

According to the authors; We have followed our usual tradition in that this new edition of the text is yet another thorough update of the content and its presentation. Our goal is to keep the book flexible to use, accessible to students, broad in scope, and authoritative, without adding bulk. However, it should always be borne in mind that much of the bulk arises from the numerous pedagogical features that we include (such as Worked examples, Checklists of key equations, and the Resource section), not necessarily from density of information.

The text is still divided into three parts, but material has been moved between chapters and the chapters themselves have been reorganized. We continue to respond to the cautious shift in emphasis away from classical thermodynamics by combining several chapters in Part 1 (Equilibrium), bearing in mind that some of the material will already have been covered in earlier courses. For example, material on phase diagrams no longer has its own chapter but is now distributed between Chapters 4 (Physical transformation of pure substances) and 5 (Simple mixtures). New Impact sections highlight the application of principles of thermodynamics to materials science, an area of growing interest to chemists.

In Part 2 (Structure) the chapters have been updated with a discussion of contemporary techniques of materials science—including nanoscience—and spectroscopy. We have also paid more attention to computational chemistry, and have revised the coverage of this topic in Chapter 10. Part 3 has lost chapters dedicated to kinetics of complex reactions and surface processes, but not the material, which we regard as highly important in a contemporary context. To make the material more readily accessible within the context of courses, descriptions of polymerization, photochemistry, and enzyme- and surface-catalysed reactions are now part of Chapters 21 (The rates of chemical reactions) and 22 (Reaction dynamics)—already familiar to readers of the text—and a new chapter, Chapter 23, on Catalysis.

## Contents

- Fundamentals

PART 1: Equilibrium

- The properties of gases
- Mathematical background 1: Differentiation and integration
- The First Law
- Mathematical background 2: Multivariate calculus
- The Second Law
- Physical transformations of pure substances
- Simple mixtures
- Chemical equilibrium

PART 2: Structure

- Quantum theory: introduction and principles
- Mathematical background 3: Complex numbers
- Quantum theory: techniques and applications
- Mathematical background 4: Differential equations
- Atomic structure and spectra
- Mathematical background 5: Vectors
- Molecular structure
- Mathematical background 6: Matrices
- Molecular symmetry
- Molecular spectroscopy 1: rotational and vibrational spectra
- Molecular spectroscopy 2: electronic transitions
- Molecular spectroscopy 3: magnetic resonance
- Statistical thermodynamics 1: the concepts
- Statistical thermodynamics 2: applications
- Molecular interactions
- Materials 1: macromolecules and self-assembly
- Materials 2: solids
- Mathematical background 7: Fourier series and Fourier transforms

PART 3: Change

- Molecules in motion
- The rates of chemical reactions
- Reaction dynamics
- Catalysis

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