Free download Organic Chemistry (12th international student edition) authored by Fracis A. Carey, Robert M. Giuliano, Neil T. Allison and Susan L. Bane in pdf.
According to the writers, “The text is organized according to functional groups—structural units within a molecule that are most closely identified with characteristic properties. Reaction mechanisms are emphasized early and often in an effort to develop the student’s ability to see similarities in reactivity across the diverse range of functional groups encountered in organic chemistry.
Mechanisms are developed from observations; thus, reactions are normally presented first, followed by their mechanism. In order to maintain consistency with what our students have already learned, this text presents multistep mechanisms in the same way as most general chemistry textbooks—that is, as a series of elementary steps.
Additionally, we provide a brief comment about how each step contributes to the overall mechanism. Section 1.11 “Curved Arrows, Arrow Pushing, and Chemical Reactions” provides the student with an early introduction to the notational system employed in all of the mechanistic discussions in the text.
Numerous reaction mechanisms are accompanied by potential energy diagrams. Section 5.8 “Reaction of Alcohols with Hydrogen Halides: The SN1 Mechanism” shows how the potential energy diagrams for three elementary steps are combined to give the diagram for the overall reaction.
The teaching of organic chemistry has especially benefited as powerful modeling and graphics software has become routinely available. Computer-generated molecular models and electrostatic potential maps were integrated into the third edition of this text and their number has increased in succeeding editions; also seeing increasing use are molecular orbital theory and the role of orbital interactions in chemical reactivity.”
Contents
- Structure Determines Properties
- Alkanes and Cycloalkanes: Introduction to Hydrocarbons
- Alkanes and Cycloalkanes: Conformations and cis–trans Stereoisomers
- Chirality
- Alcohols and Alkyl Halides: Introduction to Reaction Mechanisms
- Nucleophilic Substitution
- Structure and Preparation of Alkenes: Elimination Reactions
- Addition Reactions of Alkenes
- Alkynes
- Introduction to Free Radicals
- Conjugation in Alkadienes and Allylic Systems
- Arenes and Aromaticity
- Electrophilic and Nucleophilic Aromatic Substitution
- Spectroscopy
- Organometallic Compounds
- Alcohols, Diols, and Thiols
- Ethers, Epoxides, and Sulfides
- Aldehydes and Ketones: Nucleophilic Addition to the Carbonyl Group
- Carboxylic Acidsco
- Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution
- Enols and Enolates
- Amines
- Carbohydrates
- Lipids
- Amino Acids, Peptides, and Proteins
- Nucleosides, Nucleotides, and Nucleic Acids
- Synthetic Polymers
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