Free download Organic Chemistry – A Mechanistic Approach written by Tadashi Okuyama and Howard Maskill in pdf.
According to the writers, “There are different approaches to the teaching of organic chemistry at university level. In this book, we begin with a review of atomic and molecular structure and then look at factors which determine the shapes of molecules. Next, we cover acid–base (proton transfer) reactions since these are distinctive features of many reactions of organic compounds, especially ones of biological importance including reactions catalysed by enzymes. We then show that all overall reactions of organic compounds belong to one of a relatively small number of classes of reaction types.
To assist students, worked examples and exercises are embedded within each chapter; answers to in chapter exercises are provided on the book’s web site, which we describe further below. Each chapter also has a summary together with additional problems at the end. In addition, we include an early section on organic nomenclature, appendices which contain reference data, and fl ow charts encapsulating reactions and interconversions of functional groups, and a comprehensive index.”
Contents
- Atoms, Molecules, and Chemical Bonding—a Review
- Molecular Structure and Shapes of Organic Molecules
- Organic Compounds: their Functional Groups, Intermolecular Interactions, and Physical Properties
- Conformation and Strain in Molecules
- Conjugation, π-Electron Delocalization, and Aromaticity
- Acids and Bases
- Organic Reactions and the Concept of Mechanism
- Nucleophilic Addition to the Carbonyl Group in Aldehydes and Ketones
- Nucleophilic Substitution Reactions of Carboxylic Acid Derivatives
- Reactions of Carbonyl Compounds with Hydride Donors and Organometallic Reagents
- Stereochemistry and Molecular Chirality
- Nucleophilic Substitution Reactions of Haloalkanes and Related Compounds
- Elimination Reactions of Haloalkanes and Related Compounds
- Reactions of Alcohols, Ethers, Thiols, Sulfides, and Amines
- Addition Reactions of Alkenes and Alkynes
- Electrophilic Aromatic Substitution
- Enolate Ions, their Equivalents, and Reactions
- Reactions of Nucleophiles with Alkenes and Aromatic Compounds
- Polycyclic and Heterocyclic Aromatic Compounds
- Reactions involving Radicals
- Pericyclic Reactions: Cycloadditions, Electrocyclic Reactions, and Sigmatropic Rearrangements
- Rearrangement Reactions involving Polar Molecules and Ions
- Organic Synthesis
- Chemistry of Biomolecules
- Structural Determination of Organic Compounds
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