Free download Organic Chemistry – An Acid-Base Approach authored by Michael B. Smith in pdf.
The theme of this book is the premise that many if not most reactions in organic chemistry can be explained by variations of fundamental acid–base chemistry concepts. Moreover, the individual steps in many important mechanisms rely on acid–base reactions. The ability to see these relationships makes understanding organic chemistry easier and, perhaps more importantly, allows one to make predictions about reactivity when memory fails.
Apart from the acid–base theme, this book uses several techniques to assist students in their studies. A list of concepts that the student should know before reading the chapter is listed at the beginning of virtually every chapter. A list of concepts that should be known after the chapter is completed is also provided at the beginning of most chapters. Each chapter concludes with this same list of the concepts that should now have been learned, and a correlation of each concept with the homework problems is provided.
The book begins with an introduction to organic chemistry that describes what it is as well as individuals who have contributed to building organic chemistry as a scientific discipline. Chapter 2 provides a bridge between the acid–base discussions in a typical general chemistry book and those in this organic chemistry book.
- Why Is an Acid–Base Theme Important?
- Alkanes, Isomers, and an Introduction to Nomenclature
- Functional Groups
- Acids, Bases, Nucleophiles, and Electrophiles
- Chemical Reactions, Bond Energy, and Kinetics
- Rotamers and Conformation
- Stereoisomers: Chirality, Enantiomers, and Diastereomers
- Acid–Base Reactions of π-Bonds
- Nucleophiles: Lewis Base-Like Reactions at sp3 Carbon
- Base-Induced Elimination Reactions
- Substitution and Elimination Reactions Can Compete
- Spectroscopic Methods of Identification
- Organometallic Reagents
- Carbonyl Compounds: Structure, Nomenclature, Reactivity
- Reactions of Aldehydes and Ketones
- Carboxylic Acid Derivatives and Acyl Substitution
- Aromatic Compounds and Benzene Derivatives
- Enolate Anions: Acyl Addition and Acyl Substitution
- Difunctional Molecules: Dienes and Conjugated Carbonyl Compounds
- Difunctional Molecules: Pericyclic Reactions
- Disconnections and Synthesis
- Heteroaromatic Compounds
- Multifunctional Compounds: Amino Acids and Peptides
- Multifunctional Compounds: Carbohydrates
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