Free download Writing Reaction Mechanisms in Organic Chemistry (3rd edition) authored by Kenneth A. Savin in pdf.
For the third edition of this text, the focus on the how of writing organic reaction mechanisms remains the foremost objective. The book has been expanded with a new chapter focused on oxidation and reduction mechanisms as well as new material throughout the text. Although oxidation and reduction reactions were considered for previous versions of the text, it was decided that this important and yet often underrepresented topic should be included to better equip the reader.
This new chapter is set up to allow students to see how our understanding of mechanisms has developed and apply what they have learned in the earlier chapters of the book to a greater number of situations and more sophisticated systems. We have added new problems throughout the text to update and provide illustrative examples to the text that will aid in identifying key situations and patterns.
The oxidations chapter also allows us to touch on other mechanistic topics including organometallics, stereochemistry, radiolabeling, and a more philosophical view of the mechanistic models we are applying. This new chapter, as well as the changes to the previous chapters, has all been done with consideration to the ultimate length of the book and the goal of keeping it portable and reasonable in length.
Contents
- Introduction – Molecular Structure and Reactivity
- General Principles for Writing Reaction Mechanisms
- Reactions of Nucleophiles and Bases
- Reactions Involving Acids and Other Electrophiles
- Radicals and Radical Anions
- Pericyclic Reactions
- Oxidations and Reductions
- Additional Problems
- Appendix A – Lewis Structures of Common Functional Groups
- Appendix B – Symbols and Abbreviations Used in Chemical Notation
- Appendix C – Relative Acidities of Common Organic and Inorganic Substances
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