Free download Organic Chemistry: 100 Must-Know Mechanisms (2nd Edition) by Roman A. Valiulin in pdf.
This edition of Organic Chemistry: 100 Must-Know Mechanisms is an enriched and improved version of the first book with over 40 new illustrations. It builds upon the existing 100 fundamental mechanisms mentioned in the previous book and adds other mechanisms related to the original 100 with engaging, supplementary examples.
The book is also fine-tuned with features that can help broaden its usefulness to earlier stage students of chemistry and related sciences.
Formal Lewis (dot) structures are added to all the previously mentioned intermediates in each mechanism, keeping track of the movement of electrons and making the schemes more comprehensive.
This improvement is a valuable enhancement for those still learning organic chemistry and expands usefulness to undergraduate students and college students in STEM fields whose area of major concentration is not chemistry.
The original 100 mechanistic schemes are also visually improved: the chemical structures are more vivid and consistent throughout the book. Additionally, newly formed bonds are highlighted in red color and accentuated using bold lines for each final product or key intermediate.
This edition continues in the tradition of the first: presenting information efficiently by using clear, balanced, and intuitive visuals and infographic diagrams. Like a stone sculpture, this version is a refined and more finely chiseled version of the first.
The goal is to build upon what worked well, update the content where needed, and to add key pieces of information or notation, with the ultimate objective of making the book more useful to more students of chemistry and the sciences.
Contents
- Electrophilic Addition Mechanism
- Nucleophilic Substitution Mechanism
- Aromatic Electrophilic Substitution Mechanism
- Aromatic Nucleophilic Substitution Mechanism
- Aromatic Radical Nucleophilic Substitution Mechanism
- Elimination Mechanism
- Acyloin Condensation
- Alkyne Zipper Reaction
- Arbuzov Reaction
- Arndt–Eistert Synthesis
- Baeyer–Villiger Oxidation
- Barton Decarboxylation
- Baylis–Hillman Reaction
- Beckmann Rearrangement
- Benzoin Condensation
- Benzyne Mechanism
- Bergman Cyclization
- Birch Reduction
- Bischler–Napieralski Cyclization
- Brown Hydroboration
- Buchwald–Hartwig Cross-Coupling
- Cannizzaro Reaction
- Chan–Evans–Lam Cross-Coupling
- Chichibabin Amination
- Claisen Condensation
- Claisen Rearrangement
- Cope Elimination
- Cope Rearrangement
- Criegee and Malaprade Oxidation
- CuAAC
- Curtius Rearrangement
- Darzens Condensation
- Dess–Martin Oxidation
- Diazotization (Diazonium Salt)
- Diels–Alder Cycloaddition
- Di-π-Methane Rearrangement
- Favorskii Rearrangement
- Fischer Indole Synthesis
- Friedel–Crafts Acylation and Alkylation
- Gabriel Synthesis
- Gewald Reaction
- Glaser–Eglinton–Hay Coupling
- Grignard Reaction
- Grob Fragmentation
- Haloform Reaction
- Heck Cross-Coupling
- Hell–Volhard–Zelinsky Reaction
- Hiyama Cross-Coupling
- Hofmann Elimination
- Horner–Wadsworth–Emmons Olefination
- Jones Oxidation
- Kucherov Reaction
- Kumada Cross-Coupling
- Ley–Griffith Oxidation
- Liebeskind–Srogl Cross-Coupling
- Mannich Reaction
- McMurry Coupling
- Meerwein–Ponndorf–Verley Reduction
- Michael Addition
- Minisci Reaction
- Mitsunobu Reaction
- Miyaura Borylation
- Mukaiyama RedOx Hydration
- Nazarov Cyclization
- Nef Reaction
- Negishi Cross-Coupling
- Norrish Type I and II Reactions
- Olefin (Alkene) Metathesis
- Oppenauer Oxidation
- Ozonolysis
- Paal–Knorr Syntheses
- Paternò–Büchi Reaction
- Pauson–Khand Reaction
- Peptide (Amide) Coupling
- Pictet–Spengler Reaction
- Pinacol–Pinacolone Rearrangement
- Polonovski Reaction
- Prilezhaev Epoxidation
- Prins Reaction
- Pummerer Rearrangement
- Ramberg–Bäcklund Rearrangement
- Reformatsky Reaction
- Robinson Annulation
- Shapiro Reaction
- Sonogashira Cross-Coupling
- Staudinger Reaction
- Steglich Esterification
- Stille Cross-Coupling
- Suzuki Cross-Coupling
- Swern Oxidation
- Ugi Reaction
- Ullmann Aryl–Aryl Coupling
- Upjohn Dihydroxylation
- Vilsmeier–Haack Reaction
- Wacker Oxidation
- Wagner–Meerwein Rearrangement
- Weinreb Ketone Synthesis
- Wittig Reaction
- Wohl–Ziegler Reaction
- Wolff–Kishner Reduction
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