Free download Chemical Kinetics: From Molecular Structure to Chemical Reactivity (2nd edition) written by Luis Arnaut in pdf.
Chemical Kinetics takes the reader on a journey through the world of chemical changes, guided by explanations of how molecular structures evolve over time.
For less-experienced travellers, this book provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For seasoned travellers, this book takes them to a viewpoint where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena.
The second edition of Chemical Kinetics: From Molecular Structure to Chemical Reactivity builds on the success of the first edition to provide an understanding of chemical reactions rates and their relations to reactants properties, reaction media, and external factors. The new edition is fully revised and updated, reflecting the latest developments in the field and expanding its scope.
Written in an accessible style, this book is primarily intended for an audience of undergraduate and graduate students in Chemistry, Chemical Engineering, Biochemistry, and Pharmacy, all of whom need to understand how to measure, evaluate, and predict rates of molecular transformations. Beginners, presumed to have a basic knowledge of calculus, are offered a simple rationale for measuring, interpreting, and predicting rates of chemical reactions.
This book makes rigour and exactitude accessible by illustrating all the theories and mechanisms with recent examples. Some examples are described with sufficient detail and simplicity to be used in general chemistry and lab courses. The gap for specialists in the field is bridged with sections of increasing complexity in the chapters discussing experimental techniques, theories of reaction dynamics and kinetics in thermalized systems, and rates of prototypical reactions (atom transfer, proton transfer, substitution reactions, and catalysis).
Contents
- Introduction
- Reaction rate laws
- Experimental methods
- Reaction order and rate constants
- Collisions and molecular dynamics
- Reactivity in thermalised systems
- Relationships between structure and reactivity
- Unimolecular reactions
- Elementary reactions in solution
- Reactions on surfaces
- Substitution reactions
- Chain reactions
- Acid base catalysis and proton-transfer reactions
- Enzymatic catalysis
- Pharmacokinetics
- Transitions between electronic states
- Electron-transfer reactions
- Oscillatory reactions
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