Free download Organic Chemistry – An Acid-Base Approach (3rd edition) written by Michael B. Smith in pdf.
According to the writer of the book, “Every chapter in this third edition has been extensively revised. Chapter 1 presents a brief history of organic chemistry. Chapter 1 also introduces 19 scientists who made significant contributions to organic chemistry but whose work has not been reported in a textbook prior to this work.
Chapters 2 and 6 introduce acid–base reactions based on general chemistry principles and the organic chemistry of organic chemicals. Chapter 6 elaborates the acid–base properties of organic functional groups. The structure of alkanes and the fundamentals of nomenclature are presented in Chapter 4.
Chapter 5 introduces important functional groups, along with their nomenclature. The energy considerations that are important to reactions in organic chemistry are discussed in Chapter 7. Bond rotation and conformations are discussed in Chapter 8, as well as a discussion of large ring compounds. The concepts and applications of chirality and stereochemistry are discussed in Chapter 9.
Many classical chemical reactions are presented in this revision, but there are also reactions used in modern organic chemistry. These new reactions are presented to show how organic chemistry has matured and changed as a science over the last 50 years or so.
The homework in the third edition is largely the same as that in the second edition, but there are changes. This decision was taken with the recognition that substantive changes have been made in the discussions of every chapter, as well as the examples that are used.”
Contents
- Introduction
- Why Is an Acid-Base Theme Important?
- Bonding
- Alkanes, Isomers, and an Introduction to Nomenclature
- Functional Groups
- Acids, Bases, and Nucleophiles
- Chemical Reactions, Bond Energy, and Kinetics
- Conformations
- Stereoisomers: Chirality, Enantiomers, and Diastereomers
- Acid–Base Reactions of pi-Bonds: Addition Reactions
- Substitution Reactions
- Elimination and p-Bond-Forming Reactions
- Spectroscopic Methods of Identification
- Organometallics
- Oxidation
- Reactions of Aldehydes and Ketones
- Reduction
- Carboxylic Acid Derivatives and Acyl Substitution
- Aromatic Compounds and Benzene Derivatives
- Enolate Anions: Acyl Addition and Acyl Substitution
- Difunctional Molecules: Dienes and Conjugated Carbonyl Compounds
- Difunctional Molecules: Pericyclic Reactions
- Heteroaromatic Compounds
- Multifunctional Compounds: Amines, Amino Acids and Peptides
- Multifunctional Compounds: Carbohydrates
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