Free download The Art of Writing Reasonable Organic Reaction Mechanisms (3rd edition) by Robert B. Grossman in pdf.
The Art of Writing Reasonable Organic Reaction Mechanisms (3rd Edition) is designed for intermediate organic chemistry students, this text guides readers in constructing logical mechanisms for organic transformations.
Instead of focusing on overall reactions, it organizes discussions by mechanism types and reaction conditions. Each mechanism is accompanied by worked examples, with strategically placed “common error alerts” to help students avoid mistakes.
Every chapter concludes with an extensive problem set. Drawing from both his own research and current literature, the author covers a broad spectrum of modern organic chemistry, including a dedicated chapter on transition metal-mediated or catalyzed reactions.
While addressing emerging topics, the text ensures thorough coverage of traditional material. Assuming a foundational knowledge of organic chemistry, it serves as both a course textbook and a valuable self-study resource, particularly for students preparing for qualifying exams.
This book definitely does not attempt to teach specific synthetic procedures, reactions, or strategies. Only rarely will you be asked to predict the products of a particular reaction. This book also does not attempt to teach physical organic chemistry (i.e., how mechanisms are proven or disproven in the laboratory).
Before you can learn how to determine reaction mechanisms experimentally, you must learn what qualifies as a reasonable mechanism in the first place. Isotope effects, Hammett plots, kinetic analysis, and the like are all left to be learned from other textbooks.
Contents
- The Basics
- Polar Reactions Under Basic Conditions
- Polar Reactions Under Acidic Conditions
- Pericyclic Reaction
- Free-Radical Reactions
- Transition-Metal-Mediated and -Catalyzed Reactions
- Mixed-Mechanism Problems
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