Free download Organic Chemistry Theory, Reactivity and Mechanisms in Modern Synthesis written by Vogel Pierre and Kendall N. Houk in pdf.
According to the authors, “This book introduces and documents models that enable chemists to answer these questions and to understand the reasons behind the answers. The methods will be illustrated with a large number of reactions that have a wide practical value in synthesis and biology. Reactions involving organic, organometallic, and biochemically important reactants and catalysts will be presented.
We teach the tools that can be used to understand Nature and to control and create new chemistry to achieve a better world. Given specific combinations of solvent, concentration, temperature, pressure, the presence or absence of catalysts and inhibitors, light, or other types of radiation, a given system of reactants will be converted into a mixture of products.
Rates of product formation or attainment of equilibria define chemical reactivity. Living systems are made of ensembles of molecules that are connected through ensembles of chemical reactions.
Chemical structures, stability, and reactivity are governed by thermodynamics (Chapters 1 and 2) and kinetics (Chapter 3). Thermodynamics dictates how atoms assemble into stable molecules and how molecules assemble into supramolecular systems.
Kinetics quantitates the rates at which molecules are transformed into other molecules or assemblies of molecules under specific conditions. Our preface gives a brief history of chemistry and shows how heat exchange is fundamental to produce and modify chemicals.”
Contents
- Equilibria and Thermochemistry
- Additivity Rules for Thermodynamic Parameters and Deviations
- Rates of Chemical Reactions
- Molecular Orbital Theories
- Pericyclic Reactions
- Organic Photochemistry
- Catalytic Reactions
- Transition-Metal-Catalyzed C—C Bond Forming Reactions
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